Effectiveness of a natural coagulant based on common mallow (Malva sylvestris) in urban wastewater treatment.

This study evaluated the effectiveness of a natural coagulant based on common mallow (Malva sylvestris) to remove turbidity in urban wastewater. A 22 factorial design was selected to determine the optimal dose and the working pH of the natural coagulant. Its potential was studied in 50.0-450 mg/L and 4.00-10.0 ranges of doses and pH, respectively. A simplex lattice mixture evaluated its effectiveness as a coagulant aid combined with aluminum sulfate (conventional coagulant). Mixture proportions 0.000-1.00 were studied for each component, finding the proportion more effective. Results showed that the coagulation treatment could be feasible since a turbidity removal efficiency of 73.7% can be achieved under optimal conditions (50.0 mg/L and pH of 10.0). Likewise, a turbidity removal of 58.9% is obtained using 250 mg/L and maintaining wastewater pH (7.45). This efficiency can be increased using 31.0% natural coagulant mixed with 69.0% aluminum sulfate at 250 mg/L without modifying the wastewater pH. This improvement was associated with the natural coagulant's high molecular weight and long-chained structure since these properties enhance settling time, floc size and strength, and low sludge production. These results support using common mallow as a natural coagulant, making its use more feasible in alkaline water pH or as a coagulant aid combined with aluminum sulfate for urban wastewater treatment. A cost of USD 370/Kg of natural coagulant was estimated, which is higher than conventional coagulants. However, a cost-effectiveness analysis of its implementation should be performed since process scaling costs could significantly reduce its price.

Efficient removal of triclosan from water through activated carbon adsorption and photodegradation processes.

This study investigated the application of adsorption with activated carbons (ACs) and photodegradation to reduce the concentration of triclosan (TCS) in aqueous solutions. Concerning adsorption, ACs (Darco, Norit, and F400) were characterised and batch experiments were performed to elucidate the effect of pH on equilibrium. The results showed that at pH = 7, the maximum adsorption capacity of TCS onto the ACs was 18.5 mg g-1 for Darco, 16.0 mg g-1 for Norit, and 15.5 mg g-1 for F400. The diffusional kinetic model allowed an adequate interpretation of the experimental data. The effective diffusivity varied and increased with the amount of TCS adsorbed, from 1.06 to 1.68 × 10-8 cm2 s-1. In the case of photodegradation, it was possible to ensure that the triclosan molecule was sensitive to UV light of 254 nm because the removal was over 80 % using UV light. The removal of TCS increased in the presence of sulfate radicals. It was possible to identify 2,4-dichlorophenol as one of the photolytic degradation products of triclosan, which does not represent an environmental hazard at low concentrations of triclosan in water. These results confirm that the use of AC Darco, Norit, and F400 and that photodegradation processes with UV light and persulfate radicals are effective in removing TCS from water, reaching concentration levels that do not constitute a risk to human health or environmental hazard. Both methods effectively eliminate pollutants with relatively easy techniques to implement.

Fundamentals in applications of algae biomass: A review.

Algae play an extremely important ecological role. They form the basis of trophic webs, produce oxygen that allows the respiration of many of the organisms in aquatic environments, absorb CO2, and serve as refuge areas and habitats for thousands of species. Many species can also absorb organic pollutants from seawater. Algae have been used for many centuries by humans as a source of food, fertilizer, fodder, and for the extraction of compounds with antifungal, antiviral, anticancer, and antibacterial properties. More recently, some species have been used for the production of biofuels. It has been shown that mixing small proportions of algae with the feed of cattle can reduce methane emissions from their digestive activity by more than 95%. One of the most widespread but least known applications of algae is the extraction of their phycocolloids for utilization in food, pharmaceutical, wine, and textile industries, among others. These compounds have gelling, stabilizing, and thickening properties and are therefore frequently included in creams, ice creams, cheeses, jellies, flavored milks, sauces, shampoos, medications, toothpaste, and many other products. The phycocolloids agar and carrageenan are extracted from red algae, whereas alginate is extracted from brown algae, being used in dental impressions, emulsifying lotions, and paints, among others, and in the preparation of wine and beer. Algae are of particular interest in the research and development of new biosorbent materials, not only because of their high adsorption capacity, but also because they are present in the seas and oceans in abundant and easily accessible quantities. Marine algae are a promising biosorbent for the removal of heavy metals and various pollutants and, due to their intrinsic characteristics, have received increasing attention in recent decades. Their application as biosorbents for the sorption of heavy metals and radionuclides could be interpreted as the use of waste to remove waste. Algae have attracted particular interest in the field of biotechnology for economic reasons, given that large amounts are naturally produced and left lying on beaches as waste material. The composition of algae biomass makes it a promising candidate for an extensive list of applications that continues to lengthen. The development of appropriate technologies and policies can transform the presence of algae in coastal ecosystems from an unpleasant and potentially harmful phenomenon into a source of major benefits. This review discusses the capacity of algae biomass to remove pollutants and also delves into its applicability in the production of dyes, oils, and biofuels and for animal feed and fertilizer industries, among others. Further research is warranted on strategies to convert a biomass that is currently considered waste into a means of addressing environmental problems.

Valorization of Sargassum Biomass as Potential Material for the Remediation of Heavy-Metals-Contaminated Waters.

Sargassum algae has become a major environmental issue due to its abundance in the Pacific Ocean with hundreds of tons reaching the beaches of the Mexican Caribbean every year. This generates large quantities of decomposing organic matter that have a negative impact on the region's economy and ecosystems. Sargassum valorization has turned out to be a fundamental aspect to mitigate its environmental impact. This study proposes the use and application of untreated Sargassum biomass for the decontamination of waters polluted with lead (Pb) and cadmium (Cd) through single and binary adsorption tests. Physicochemical and textural properties examined by SEM, XRD, and FT-IR elucidated that Sargassum biomass is viable to be used as a potential environmental benign adsorbent, exhibiting Cd(II) and Pb(II) adsorption capacities as high as 240 mg g-1 and 350 mg g-1, respectively, outperforming conventionally used adsorbents. This is attributed to its morphology, favorable surface charge distribution, and the presence of -OH and -COH groups. A strong affinity between the biomass and metal pollutants was evidenced by a thermodynamics study, showing a spontaneous and endothermic process. This work sets a practical route for the utilization of the Sargassum biomass, demonstrating its applicability as a potential material for heavy-metal-polluted water remediation, making a substantial contribution to a circular economy system.